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Are multiple oxygen species selective in ethylene epoxidation on silver?

The nature of the oxygen species active in ethylene epoxidation is a long-standing question. While the structure of the oxygen species that participates in total oxidation (nucleophilic oxygen) is known the atomic structure of the selective species (electrophilic oxygen) is still debated. Here, we u...

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Библиографические подробности
Опубликовано в: :Chem Sci
Главные авторы: Carbonio, Emilia A., Rocha, Tulio C. R., Klyushin, Alexander Yu., Píš, Igor, Magnano, Elena, Nappini, Silvia, Piccinin, Simone, Knop-Gericke, Axel, Schlögl, Robert, Jones, Travis E.
Формат: Artigo
Язык:Inglês
Опубликовано: Royal Society of Chemistry 2017
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Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC5874983/
https://ncbi.nlm.nih.gov/pubmed/29629166
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04728b
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