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Ruthenium Catalyzed Hydrohydroxyalkylation of Isoprene with Heteroaromatic Secondary Alcohols: Isolation and Reversible Formation of the Putative Metallacycle Intermediate
Heteroaromatic secondary alcohols react with isoprene to form products of hydrohydroxyalkylation in the presence of ruthenium(0) catalysts generated from Ru(3)(CO)(12) and tricyclohexylphosphine, enabling direct conversion of secondary to tertiary alcohols in the absence of premetallated reagents or...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3855325/ https://ncbi.nlm.nih.gov/pubmed/24156560 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4087193 |
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