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A Synthesis of the Chlorosulfolipid Mytilipin A via a Longest Linear Sequence of Seven Steps
The chlorosulfolipid mytilipin A has been synthesized in racemic form in only seven steps and in enantioenriched form in eight steps. Key transformations include a highly diastereoselective bromoallylation of a sensitive α,β-dichloroaldehyde, a kinetic resolution of a complex vinyl epoxide, a conver...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2013
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3835569/ https://ncbi.nlm.nih.gov/pubmed/23929596 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201304565 |
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