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General Approach to the Synthesis of the Chlorosulfolipids Danicalipin A, Mytilipin A, and Malhamensilipin A in Enantioenriched Form

[Image: see text] A second-generation synthesis of three structurally related chlorosulfolipids has been developed. Key advances include highly stereocontrolled additions to α,β-dichloroaldehydes, kinetic resolutions of complex chlorinated vinyl epoxide intermediates, and Z-selective alkene cross me...

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Bibliographic Details
Main Authors: Chung, Won-jin, Carlson, Joseph S., Vanderwal, Christopher D.
Format: Artigo
Language:Inglês
Published: American Chemical Society 2014
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3954434/
https://ncbi.nlm.nih.gov/pubmed/24494597
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo5000829
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