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Cyclic Metalated Nitriles: Stereoselective Cyclizations to cis- and trans-Hydrindanes, Decalins, and Bicyclo[4.3.0]undecanes

Metalated nitriles are nucleophilic chameleons whose precise identity is determined by the nature of the metal, the solvent, the temperature, and the structure of the nitrile. The review surveys the different structural types and their cyclization trajectories to show how to selectively tune the met...

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Bibliographic Details
Main Authors: Fleming, Fraser F., Gudipati, Subramanyham
Format: Artigo
Language:Inglês
Published: 2008
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3831376/
https://ncbi.nlm.nih.gov/pubmed/24260015
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejoc.200800715
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