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Origins of Stereoselectivities of Dihydroxylations of cis-Bicyclo[3.3.0]octenes
Stereoselectivities of the dihydroxylations of cis-bicyclo[3.3.0]octene intermediates for a projected total synthesis of chromodorolide A have been explored experimentally. The reaction occurs unexpectedly on the apparently more hindered (concave) face; this result has been explained through computa...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3460691/ https://ncbi.nlm.nih.gov/pubmed/22954350 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3075538 |
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