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Development of Asymmetric Deacylative Allylation

Herein we present the development of asymmetric deacylative allylation of ketone enolates. The reaction directly couples readily available ketone pronucleophiles with allylic alcohols using facile retro-Claisen cleavage to form reactive intermediates in situ. The simplicity and robustness of the rea...

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Detalles Bibliográficos
Main Authors: Grenning, Alexander J., Van Allen, Christie K., Maji, Tapan, Lang, Simon B., Tunge, Jon A.
Formato: Artigo
Idioma:Inglês
Publicado: 2013
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3827786/
https://ncbi.nlm.nih.gov/pubmed/23734611
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo400793a
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