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Deacylative allylation: allylic alkylation via retro-Claisen activation
A new method for allylic alkylation of a variety of relatively non-stabilized carbon nucleophiles is described herein. In this process of “deacylative allylation” the coupling partners, an allylic alcohol and a ketone pronucleophile, undergo in situ retro-Claisen activation to generate an allylic ac...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3179378/ https://ncbi.nlm.nih.gov/pubmed/21830777 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja205717f |
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