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Synthesis of axially chiral gold complexes and their applications in asymmetric catalyses

Several novel chiral N-heterocyclic carbene and phosphine ligands were prepared from (S)-BINOL. Moreover, their ligated Au complexes were also successfully synthesized and characterized by X-ray crystal diffraction. A weak gold-π interaction between the Au atom and the aromatic ring in these gold co...

Полное описание

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Библиографические подробности
Главные авторы: Sun, Yin-wei, Xu, Qin, Shi, Min
Формат: Artigo
Язык:Inglês
Опубликовано: Beilstein-Institut 2013
Предметы:
Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC3817475/
https://ncbi.nlm.nih.gov/pubmed/24204435
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.261
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