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Role of Oxido Incorporation and Ligand Lability in Expanding Redox Accessibility of Structurally Related Mn(4) Clusters

Photosystem II supports four manganese centers through nine oxidation states from manganese(II) during assembly through to the most oxidized state before O(2) formation and release. The protein-based carboxylate and imidazole ligands allow for significant changes of the coordination environment duri...

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Autores principales: Kanady, Jacob S., Tran, Rosalie, Stull, Jamie A., Lu, Luo, Stich, Troy A., Day, Michael W., Yano, Junko, Britt, R. David, Agapie, Theodor
Formato: Artigo
Lenguaje:Inglês
Publicado: 2013
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC3806640/
https://ncbi.nlm.nih.gov/pubmed/24163730
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C3SC51406D
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