X-ray absorption spectroscopic investigation of the electronic structure differences in solution and crystalline oxyhemoglobin

Hemoglobin (Hb) is the heme-containing O(2) transport protein essential for life in all vertebrates. The resting high-spin (S = 2) ferrous form, deoxy-Hb, combines with triplet O(2), forming diamagnetic (S = 0) oxy-Hb. Understanding this electronic structure is the key first step in understanding tr...

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Autores principales: Wilson, Samuel A., Green, Evan, Mathews, Irimpan I., Benfatto, Maurizio, Hodgson, Keith O., Hedman, Britt, Sarangi, Ritimukta
Formato: Artigo
Lenguaje:Inglês
Publicado: National Academy of Sciences 2013
Materias:
Physical Sciences
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC3799373/
https://ncbi.nlm.nih.gov/pubmed/24062465
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1315734110
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