On reversible H(2) loss upon N(2) binding to FeMo-cofactor of nitrogenase

Nitrogenase is activated for N(2) reduction by the accumulation of four electrons/protons on its active site FeMo-cofactor, yielding a state, designated as E(4), which contains two iron-bridging hydrides [Fe–H–Fe]. A central puzzle of nitrogenase function is an apparently obligatory formation of one...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Yang, Zhi-Yong, Khadka, Nimesh, Lukoyanov, Dmitriy, Hoffman, Brian M., Dean, Dennis R., Seefeldt, Lance C.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: National Academy of Sciences 2013
Pynciau:
Physical Sciences
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC3799348/
https://ncbi.nlm.nih.gov/pubmed/24062454
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1315852110
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