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SUPERACID-PROMOTED HYDROXYALKYLATION OF 1,2-INDANDIONES

1,2-Indandione reacts efficiently with arenes to give 2,2-diaryl-1-indanones by the hydroxyalkylation reaction. The Brønsted superacid CF(3)SO(3)H (triflic acid) is an effective catalyst for these condensation reactions. The requisite 1,2-indandiones were prepared from the 1-indanones.

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Bibliografske podrobnosti
Main Authors: Tracy, Adam F., Abbott, Matthew P., Klumpp, Douglas A.
Format: Artigo
Jezik:Inglês
Izdano: 2013
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3797623/
https://ncbi.nlm.nih.gov/pubmed/24143034
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1080/00397911.2012.693239
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