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Superacid-promoted additions involving vinyl-substituted pyrimidines, quinoxalines, and quinazolines: mechanisms correlated to charge distributions

The superacid-promoted reactions of vinyl-substituted N-heterocycles have been studied. Diprotonated pyrimidines, quinoxalines, and quinazolines exhibit an unusual regioelectronic effect that controls the type of addition reaction observed. Depending on the ring position of the vinyl-substituent, ei...

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Bibliografische gegevens
Hoofdauteurs: Zhang, Yiliang, Sheets, Matthew R., Raja, Erum K., Boblak, Kenneth N., Klumpp, Douglas A.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2011
Onderwerpen:
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3169346/
https://ncbi.nlm.nih.gov/pubmed/21548654
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja202557z
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