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Pyridone Annulation via Tandem Curtius Rearrangement/6π-Electrocyclization: Total Synthesis of (−)-Lyconadin C

[Image: see text] A concise, enantioselective total synthesis of the Lycopodium alkaloid (−)-lyconadin C was achieved in 12 steps and high overall yield. Key features include construction of a luciduline congener through Mannich-type cyclization and a one-pot, tandem Curtius rearrangement/6π-electro...

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Bibliografski detalji
Glavni autori: Cheng, Xiayun, Waters, Stephen P.
Format: Artigo
Jezik:Inglês
Izdano: 2013
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3788595/
https://ncbi.nlm.nih.gov/pubmed/23909645
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol401954f
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