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Tandem 6Π-Electrocyclization and Cycloaddition of Nitrodienes to Yield Multicyclic Nitroso Acetals
[Image: see text] Upon heating, nitrodienes rearrange through 6Π-electrocyclization to form nitronate intermediates, which can be captured through tandem [3 + 2] dipolar cycloadditions to form highly functionalized nitroso acetals. The one-pot, two-step domino process is highly efficient, proceeding...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2903206/ https://ncbi.nlm.nih.gov/pubmed/20557050 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1038819 |
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