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Tandem 6Π-Electrocyclization and Cycloaddition of Nitrodienes to Yield Multicyclic Nitroso Acetals

[Image: see text] Upon heating, nitrodienes rearrange through 6Π-electrocyclization to form nitronate intermediates, which can be captured through tandem [3 + 2] dipolar cycloadditions to form highly functionalized nitroso acetals. The one-pot, two-step domino process is highly efficient, proceeding...

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Bibliografiske detaljer
Main Authors: Creech, Gardner S., Kwon, Ohyun
Format: Artigo
Sprog:Inglês
Udgivet: 2010
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2903206/
https://ncbi.nlm.nih.gov/pubmed/20557050
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1038819
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