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Differential Hydrogen Bonding in Human CYP17 Dictates Hydroxylation versus Lyase Chemistry
Raman spectra of oxygenated intermediates of Nanodisc incorporated human CYP17 in the presence of natural substrates directly confirm that substrate structure effectively alters H-bonding interactions with the critical Fe-O-O fragment so as to dictate its predisposition for one of two alternative re...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3772656/ https://ncbi.nlm.nih.gov/pubmed/23576395 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201300760 |
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