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Solution thermodynamic stability of complexes formed with the octadentate hydroxypyridinonate ligand 3,4,3-LI(1,2-HOPO): A critical feature for efficient chelation of lanthanide(IV) and actinide(IV) ions

The solution thermodynamics of water soluble complexes formed between Ce(III), Ce(IV), Th(IV) and the octadentate chelating agent 3,4,3-LI(1,2-HOPO) were investigated. Several techniques including spectrofluorimetric and automated spectrophotometric titrations were used to overcome the slow spontane...

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Autors principals: Deblonde, Gauthier J-P., Sturzbecher-Hoehne, Manuel, Abergel, Rebecca J.
Format: Artigo
Idioma:Inglês
Publicat: 2013
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3771511/
https://ncbi.nlm.nih.gov/pubmed/23855806
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic4010246
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