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Molecular mechanism of enantioselective proton transfer to carbon in catalytic antibody 14D9
Catalytic antibody 14D9 catalyzes the enantioselective protonation of prochiral enol ethers with high enantioselectivity (>99% ee) and a practical turnover (k(cat) = 0.4 s(-1)), allowing for preparative scale applications. This antibody represents one of the rare examples of catalytic antibodies...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2004
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC376184/ https://ncbi.nlm.nih.gov/pubmed/14988504 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0400263101 |
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