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Sc(3+)-triggered oxoiron(IV) formation from O(2) and its nonheme iron(II) precursor via a Sc(3+)–peroxo-Fe(3+) intermediate
We report that redox-inactive Sc(3+) can trigger O2 activation by the Fe(II)(TMC) center (TMC = tetramethylcyclam) to generate the corresponding oxoiron(IV) complex in the presence of BPh(4(−)) as an electron donor. To model a possible intermediate in the above reaction, we generated an unprecedente...
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| 主要な著者: | , , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2013
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3760346/ https://ncbi.nlm.nih.gov/pubmed/23802702 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja402645y |
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