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Pd-Catalyzed Asymmetric β-Hydride Elimination En Route to Chiral Allenes

We wish to report our preliminary results on the discovery and development of a catalytic, asymmetric β-hydride elimination from vinyl Pd(II)-complexes derived from enol triflates to access chiral allenes. To achieve this, we developed a class of chiral phosphite ligands that demonstrate high enanti...

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Detalhes bibliográficos
Main Authors: Crouch, Ian T., Neff, Robynne K., Frantz, Doug E.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3758424/
https://ncbi.nlm.nih.gov/pubmed/23488914
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja401606e
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