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Highly(≥98%) Selective Trisubstituted Alkene Synthesis of Wide Applicability via Fluoride-Promoted Pd-Catalyzed Cross-Coupling of Alkenylboranes()
(Z)-β-bromo-1-propenyl(pinacol)borane(4), recently made available in 85% yield as a ≥98% isomerically pure compound via bromoboration of 1-propyne, has been converted to β-alkyl-, aryl-, and alkenyl-substituted (Z)-2-methyl-1-alkenyl(pinacol)boranes(2a) in ca. 75% yield based on propyne via Pd-catal...
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| Main Authors: | , , , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2010
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3747006/ https://ncbi.nlm.nih.gov/pubmed/23966749 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ijch.201000051 |
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