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Highly(≥98%) Stereo- and Regioselective Trisubstituted Alkene Synthesis of Wide Applicability via 1-Halo-1-alkyne Hydroboration–Tandem Negishi-Suzuki Coupling or Organoborate Migratory Insertion Protocol

(Z)-1-Halo-1-alkenylboranes (7), preparable in 82–90% yields as ≥98% isomerically pure compounds via hydroboration of 1-halo-1-alkynes, have been converted to a wide range of trisubstituted alkenes via three different routes in the tail-to-head (T-to-H) direction, i.e., (i) Palladium-catalyzed Negis...

पूर्ण विवरण

में बचाया:
ग्रंथसूची विवरण
मुख्य लेखकों: Xu, Shiqing, Lee, Ching-Tien, Rao, Honghua, Negishi, Ei-ichi
स्वरूप: Artigo
भाषा:Inglês
प्रकाशित: 2011
विषय:
ऑनलाइन पहुंच:https://ncbi.nlm.nih.gov/pmc/articles/PMC3781585/
https://ncbi.nlm.nih.gov/pubmed/24072993
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201100420
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