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Palladium Catalyzed Cyclopropanation of Unsaturated Endoperoxides. A New Peroxide Preserving Reaction

Unsaturated bicyclic endoperoxides are efficiently cyclopropanated with excess diazomethane in the presence of catalytic Pd(OAc)(2) in a stereoselective manner. This method represents a new peroxide preserving transformation. Whereas the unsaturated endoperoxides in the [2.2.1] series are attacked b...

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書目詳細資料
Main Authors: Emerzian, Michael A., Davenport, William, Song, Jiangao, Li, Jim, Erden, Ihsan
格式: Artigo
語言:Inglês
出版: 2009
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC3746992/
https://ncbi.nlm.nih.gov/pubmed/23966902
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.200800804
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