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Palladium (II/IV) catalyzed cyclopropanation reactions: scope and mechanism
This report describes detailed studies of the scope and mechanism of a new Pd-catalyzed oxidation reaction for the stereospecific conversion of enynes into cyclopropyl ketones. Unlike related Pd(II/0), Au, and Pt-catalyzed cyclopropane-forming reactions, these transformations proceed with net invers...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2009
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2729174/ https://ncbi.nlm.nih.gov/pubmed/20161134 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2008.10.107 |
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