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Pyrrolidine catalyzed reactions of cyclopentadiene with α,β-unsaturated carbonyl compounds: 1,2- versus 1,4-additions

A systematic study of the reactions of cyclopentadiene with α,β-unsaturated carbonyl compounds in the presence of catalytic pyrrolidine-H(2)O revealed that the reactions can either proceed with a Michael attack at the β-carbon of enone, or 1,2-addition to the carbonyl, leadingeither to 4-cyclopentad...

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Detalhes bibliográficos
Publicado no:Tetrahedron
Main Authors: Coskun, Necdet, Çetin, Meliha, Gronert, Scott, Ma, Jingxiang, Erden, Ihsan
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4403802/
https://ncbi.nlm.nih.gov/pubmed/25908883
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2015.03.042
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