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A Dual Lewis Base Activation Strategy for Enantioselective Carbene-Catalyzed Annulations
A dual activation strategy integrating NHC catalysis and a second Lewis base has been developed. NHC-bound homoenolate equivalents derived from α,β-unsaturated aldehydes combine with transient reactive o-quinione methides in an enatioselective formal [4+3] fashion to access 2-benzoxopinones. The ove...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3746556/ https://ncbi.nlm.nih.gov/pubmed/23829462 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja405833m |
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