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N-Heterocyclic Carbene-Catalyzed Enantioselective Mannich Reactions with α-Aryloxyacetaldehydes
[Image: see text] N-Heterocyclic carbenes (NHCs) catalyze a new Mannich-type reaction to form β-amino acid derivatives in high yield and enantioselectivity. The reaction is initiated by the addition of an NHC to an α-aryloxyaldehyde followed by elimination of a phenoxide anion which generates an eno...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2836487/ https://ncbi.nlm.nih.gov/pubmed/20000857 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja9094044 |
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