Carbene-Catalyzed Enantioselective Decarboxylative Annulations to Access Dihydrobenzoxazinones and Quinolones

A direct decarboxylative strategy for the generation of aza-o-quinone methides (aza-o-QMs) by N-heterocyclic carbene (NHC) catalysis has been discovered and explored. This process requires no stoichiometric additives in contrast with current approaches. Aza-o-QMs react with trifluoromethyl ketones v...

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Detaylı Bibliyografya
Yayımlandı:Angew Chem Int Ed Engl
Asıl Yazarlar: Lee, Ansoo, Zhu, Joshua L., Feoktistova, Taisiia, Brueckner, Alexander C., Cheong, Paul H.-Y., Scheidt, Karl A.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2019
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Article
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC6527340/
https://ncbi.nlm.nih.gov/pubmed/30843323
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201900600
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