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Chiral Hydroxylation at the Mononuclear Nonheme Fe(II) Center of 4-(S) Hydroxymandelate Synthase – A Structure-Activity Relationship Analysis

(S)-Hydroxymandelate synthase (Hms) is a nonheme Fe(II) dependent dioxygenase that catalyzes the oxidation of 4-hydroxyphenylpyruvate to (S)-4-hydroxymandelate by molecular oxygen. In this work, the substrate promiscuity of Hms is characterized in order to assess its potential for the biosynthesis o...

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Hlavní autoři: Di Giuro, Cristiana M. L., Konstantinovics, Cornelia, Rinner, Uwe, Nowikow, Christina, Leitner, Erich, Straganz, Grit D.
Médium: Artigo
Jazyk:Inglês
Vydáno: Public Library of Science 2013
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3720870/
https://ncbi.nlm.nih.gov/pubmed/23935907
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1371/journal.pone.0068932
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