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Excited state Proton-coupled electron transfer in 8-oxoG-C and 8-oxoG-A base pairs: A time dependent density functional theory (TD-DFT) study

In a recent experiment, the repair efficiency of DNA thymine cyclobutane dimers (T<>T) on UV excitation of 8-oxoG base paired either to C or A was reported. An electron transfer mechanism from an excited charge transfer state of 8-oxoG-C (or 8-oxoG-A) to T<>T was proposed and 8-oxoG-A wa...

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Autori principali: Kumar, Anil, Sevilla, Michael D.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2013
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3717295/
https://ncbi.nlm.nih.gov/pubmed/23478652
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c3pp25430e
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