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Sulfide Oxidation by O(2): Synthesis, Structure and Reactivity of Novel Sulfide-Incorporated Fe(II) Bis(imino)pyridine Complexes

The unsymmetrical iron(II) bis(imino)pyridine complexes [Fe(II)(LN(3)SMe)(H(2)O)(3)](OTf)(2) (1), and [Fe(II)(LN(3)SMe)Cl(2)] (2) were synthesized and their reactivity with O2 was examined. Complexes 1 and 2 were characterized by single crystal X-ray crystallography, LDI-MS, (1)H-NMR and elemental a...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Widger, Leland R., Siegler, Maxime A., Goldberg, David P.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2013
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3712537/
https://ncbi.nlm.nih.gov/pubmed/23878411
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.poly.2013.01.043
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