Mild Aromatic Palladium-Catalyzed Protodecarboxylation: Kinetic Assessment of the Decarboxylative Palladation and the Protodepalladation Steps

Mechanism studies of a mild palladium catalyzed decarboxylation of aromatic carboxylic acids are described. In particular, reaction orders and activation parameters for the two stages of the transformation were determined. These studies guided development of a catalytic system capable of turnover. F...

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Bibliographic Details
Main Authors: Dickstein, Joshua S., Curto, John M., Gutierrez, Osvaldo, Mulrooney, Carol A., Kozlowski, Marisa C.
Format: Artigo
Language:Inglês
Published: 2013
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3686493/
https://ncbi.nlm.nih.gov/pubmed/23590518
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo400222c
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