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Insight into the palladium catalyzed oxidative arylation of benzofuran: Heteropoly acid oxidants evoke a Pd(II)/Pd(IV) mechanism

The effects of oxidant and organic acid additives on the oxidative cross-coupling reactions of electron rich heterocycles such as benzofuran with benzene were studied. Both regioselectivity and reaction rate could be controlled by varying the condition parameters. Furthermore, mechanistic insight wa...

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Hlavní autoři: Pereira, Kyle C., Porter, Ashley L., Potavathri, Shathaverdhan, LeBris, Alec P., DeBoef, Brenton
Médium: Artigo
Jazyk:Inglês
Vydáno: 2013
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3666950/
https://ncbi.nlm.nih.gov/pubmed/23729868
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2013.02.061
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