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Oxidant-controlled regioselectivity in the oxidative arylation of N-acetylindoles
N-Acetylindoles can be oxidatively coupled with arenes such as benzene or pentafluorobenzene in dioxane. The use of Cu(OAc)(2) as the stoichiometric oxidant produces selective arylation at the 3-position of indole while AgOAc produces selective arylation at indole’s 2-position.
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| Autors principals: | , , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2008
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2597825/ https://ncbi.nlm.nih.gov/pubmed/19652690 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2008.04.073 |
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