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Regioselective Oxidative Arylation of lndoles Bearing N-Alkyl Protecting Groups: Dual C-H Functionalization via a Concerted Metalation-Deprotonation Mechanism

The most direct method for synthesizing 2-arylindoles is the oxidative coupling of an arene with an indole. We have shown that both the activity and regioselectivity of these cross-coupling reactions are correlated to the acidity of the medium. This insight has been applied to predict the best condi...

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Detalhes bibliográficos
Main Authors: Potavathri, Shathaverdhan, Pereira, Kyle C., Gorelsky, Serge, Pike, Andrew, LeBris, Alexis P., DeBoef, Brenton
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2954267/
https://ncbi.nlm.nih.gov/pubmed/20863119
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja107159b
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