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Regioselective Oxidative Arylation of lndoles Bearing N-Alkyl Protecting Groups: Dual C-H Functionalization via a Concerted Metalation-Deprotonation Mechanism
The most direct method for synthesizing 2-arylindoles is the oxidative coupling of an arene with an indole. We have shown that both the activity and regioselectivity of these cross-coupling reactions are correlated to the acidity of the medium. This insight has been applied to predict the best condi...
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| Autors principals: | , , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2010
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2954267/ https://ncbi.nlm.nih.gov/pubmed/20863119 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja107159b |
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