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Chiral (Acyclic Diaminocarbene)Gold(I)-Catalyzed Dynamic Kinetic Asymmetric Transformation of Propargyl Esters

A highly enantioselective transformation catalyzed by chiral (acyclic diaminocarbene)gold(I) complexes is reported. The enantioselective synthesis of 2-substituted chromenyl pivalates from racemic phenol-substituted propargyl pivalates was developed. Rearrangement of the substrates in the presence o...

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書誌詳細
主要な著者: Wang, Yi-Ming, Kuzniewski, Christian N., Rauniyar, Vivek, Hoong, Christina, Toste, F. Dean
フォーマット: Artigo
言語:Inglês
出版事項: 2011
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3650467/
https://ncbi.nlm.nih.gov/pubmed/21797265
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja205068j
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