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Transannulation of 1-Sulfonyl-1,2,3-Triazoles with Heterocumulenes
Readily available 1-mesyl-1,2,3-triazoles are efficiently converted into a variety of imidazolones and thiazoles by Rh(II)-catalyzed denitrogenative reactions with isocyanates and isothiocyanates, respectively. The proposed triazolediazoimine equilibrium results in the formation of highly reactive a...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3645925/ https://ncbi.nlm.nih.gov/pubmed/23477345 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja400350c |
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