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NRVS and EPR Spectroscopy of (57)Fe-enriched [FeFe] Hydrogenase Indicate Stepwise Assembly of the H-cluster()
The [FeFe] hydrogenase from Clostridium pasteurianum (CpI) harbors four Fe–S clusters that facilitate electron transfer to the H-cluster, a ligand-coordinated six-iron prosthetic group that catalyzes the redox interconversion of protons and H(2). Here, we have used (57)Fe nuclear resonance vibration...
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| Main Authors: | , , , , , , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3644562/ https://ncbi.nlm.nih.gov/pubmed/23249091 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi301336r |
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