Wacker-Type Oxidation of Internal Alkenes using Pd(Quinox) and TBHP

[Image: see text] The Pd-catalyzed TBHP-mediated Wacker-type oxidation of internal alkenes is reported. The reaction uses 2-(4,5-dihydro-2-oxazolyl)quinoline (Quinox) as ligand and TBHP((aq)) as oxidant to deliver single ketone constitutional isomer products in a predictable fashion from electronica...

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Hauptverfasser: DeLuca, Ryan J., Edwards, Jennifer L., Steffens, Laura D., Michel, Brian W., Qiao, Xiaoxiao, Zhu, Chunyin, Cook, Silas P., Sigman, Matthew S.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2013
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3615722/
https://ncbi.nlm.nih.gov/pubmed/23363387
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo302638v
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