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On the Mechanism of the Palladium-Catalyzed TBHP-Mediated Wacker-Type Oxidation of Alkenes using Quinoline-2-Oxazoline Ligands

The mechanism of the tert-butylhydroperoxide-mediated, Pd(quinox)-catalyzed Wacker-type oxidation was investigated to evaluate the hypothesis that a selective catalyst-controlled oxidation could be achieved by rendering the palladium coordinatively saturated using a bidentate amine ligand. The uniqu...

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Hlavní autoři: Michel, Brian W., Steffens, Laura D., Sigman, Matthew S.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2011
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3113657/
https://ncbi.nlm.nih.gov/pubmed/21553838
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2017043
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