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A General and Efficient Catalyst System for a Wacker-Type Oxidation Using TBHP as the Terminal Oxidant: Application to Classically Challenging Substrates

[Image: see text] Utilizing the rapidly synthesized Quinox ligand and commercially available aqueous TBHP, a Wacker-type oxidation has been developed, which efficiently converts the traditionally challenging substrate class of protected allylic alcohols to the corresponding acyloin products. Additio...

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Main Authors: Michel, Brian W., Camelio, Andrew M., Cornell, Candace N., Sigman, Matthew S.
Formato: Artigo
Idioma:Inglês
Publicado: 2009
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC2763354/
https://ncbi.nlm.nih.gov/pubmed/19364100
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja901212h
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