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BOROX Catalysis: Self-assembled AMINO-BOROX and IMINO-BOROX Chiral Brønsted Acids in a Five Component Catalyst Assembly/Catalytic Asymmetric Aziridination
A five-component catalyst assembly/aziridination reaction is described starting from an aldehyde, an amine, ethyl diazoacetate, B(OPh)(3) and a molecule of a vaulted biaryl ligand (VAPOL or VANOL). A remarkable level of chemo-selectivity was observed since while 10 different products could have resu...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2012
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3605743/ https://ncbi.nlm.nih.gov/pubmed/22947019 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo301064u |
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