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Regioselective Opening of myo-Inositol Orthoesters: Mechanism and Synthetic Utility
[Image: see text] Acid hydrolysis of myo-inositol 1,3,5-orthoesters, apart from orthoformates, exclusively affords the corresponding 2-O-acyl myo-inositol products via a 1,2-bridged five-membered ring dioxolanylium ion intermediate observed by NMR spectroscopy. These C-2-substituted inositol derivat...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical Society
2013
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3601604/ https://ncbi.nlm.nih.gov/pubmed/23438216 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo3027774 |
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