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Enantioselective Heck Arylations of Acyclic Alkenyl Alcoholsx Using a Redox-Relay Strategy

Progress in the development of asymmetric Heck couplings of arenes and acyclic olefins has been limited by a tenuous understanding of the factors that dictate selectivity in migratory insertion and β-hydride elimination. On the basis of key mechanistic insight recently garnered in the exploration of...

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Autors principals: Werner, Erik W., Mei, Tian-Sheng, Burckle, Alexander J., Sigman, Matthew S.
Format: Artigo
Idioma:Inglês
Publicat: 2012
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3583361/
https://ncbi.nlm.nih.gov/pubmed/23239733
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.1229208
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