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Fluorescence of Tryptophan in Designed Hairpin and Trp-cage Miniproteins: Measurements of Fluorescence Yields and Calculations by Quantum Mechanical Molecular Dynamics Simulations

The quantum yield of tryptophan (Trp) fluorescence was measured in 30 designed miniproteins (17 β-hairpins and 13 Trp-cage peptides), each containing a single Trp residue. Measurements were made in D(2)O and H(2)O to distinguish between fluorescence quenching mechanisms involving electron and proton...

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Detalhes bibliográficos
Main Authors: McMillan, Andrew W., Kier, Brandon L., Shu, Irene, Byrne, Aimee, Andersen, Niels H., Parson, William W.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3581364/
https://ncbi.nlm.nih.gov/pubmed/23330783
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp3097378
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