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Use of Metallopeptide Based Mimics Demonstrates That The Metalloprotein Nitrile Hydratase Requires Two Oxidized Cysteinates For Catalytic Activity
Nitrile hydratases (NHases) are non-heme Fe(III) or non-corrin Co(III) containing metalloenzymes that possess an N(2)S(3) ligand environment with nitrogen donors derived from amidates and sulfur donors derived from cysteinates. A closely related enzyme is thiocyanate hydrolase (SCNase), which posses...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3570060/ https://ncbi.nlm.nih.gov/pubmed/20831172 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic101765h |
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