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Sequential oxidations of thiolates and the cobalt metallocenter in a synthetic metallopeptide: Implications for the biosynthesis of nitrile hydratase
Cobalt nitrile hydratases (Co-NHase) contain a catalytic cobalt (III) ion coordinated in an N(2)S(3) first coordination sphere comprised of two amidate nitrogens and three cysteine-derived sulfur donors: a thiolate (-SR), a sulfenate (-S(R)O(−)), and a sulfinate (-S(R)O(2)(−)). The sequence of biosy...
Αποθηκεύτηκε σε:
| Κύριοι συγγραφείς: | , , , , , , , |
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| Μορφή: | Artigo |
| Γλώσσα: | Inglês |
| Έκδοση: |
2013
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| Θέματα: | |
| Διαθέσιμο Online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4046696/ https://ncbi.nlm.nih.gov/pubmed/23587023 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic400171z |
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