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Quantitation of Ligand Effect in oxo-transfer reactions from dioxo-Mo(VI) trispyrazolyl borate complexes

The oxygen atom transfer reactivity (OAT) from dioxo-Mo(VI) complexes of hydrotrispyrazolyl borate (hydrotris(3,5-dimethylpyrazolyl)borate, Tp(Me2); hydrotris(3-isopropylpyrazol-1-yl)borate, Tp(iPr)) to tertiary phosphines (PMe(3), PMe(2)Ph, PEt(3), PEt(2)Ph, PBu(n)(3), PMePh(2), or PEtPh(2)) has be...

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Detalhes bibliográficos
Main Authors: Basu, Partha, Kail, Brian W., Adams, Andrew K., Nemykin, Victor N.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3566299/
https://ncbi.nlm.nih.gov/pubmed/23212540
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c2dt32349d
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